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À propos de : Cooperative Ratiometric Chemosensors: Pinwheel Receptors withan Integrated Fluorescence System        

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  • Cooperative Ratiometric Chemosensors: Pinwheel Receptors withan Integrated Fluorescence System
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  • The synthesis and fluorescent properties of a second generation cooperative chemical sensor aredescribed. The sensor has two interacting binding pockets for cooperative recognition of two analytes.Cooperative binding activates a ratiometric fluorescent response via formation of an excimer.Binding was characterized by NMR, absorption, and fluorescence spectroscopy. The advantages ofseparating the recognition elements from the fluorescent response elements are discussed.
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