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À propos de : Total Synthesis of (±)-Asteriscanolide        

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  • Total Synthesis of (±)-Asteriscanolide
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  • The total synthesis of asteriscanolide (1) has been achieved by taking advantage on anintermolecular Pauson−Khand cycloaddition and a ring-closing metathesis as key bond-formingtransformations. The approach incorporates the cyclooctane stereogenic center prior to ringformation. Interestingly, the ring-closing metathesis generates a new eight-membered ring withan “in−out” intrabridgehead relationship.
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