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À propos de : Electrolytic Partial Fluorination of Organic Compounds. 55.Highly Regio- and Stereoselective Anodic Monofluorination of2,3-Dihydrochroman-4-one and Chromone Derivatives        

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  • Electrolytic Partial Fluorination of Organic Compounds. 55.Highly Regio- and Stereoselective Anodic Monofluorination of2,3-Dihydrochroman-4-one and Chromone Derivatives
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  • Anodic monofluorination at the position α to the oxygen atom of the (E)-3-benzylidene-2,3-dihydrochroman-4-one derivatives was successfully carried out to provide the corresponding 2-fluorochromanones selectively. This is the first regioselective electrochemical fluorination of fused-type,oxygen-containing heterocyclic compounds. Anodic fluorination of a chromone derivative also gavea similar fluorinated chromanone stereoselectively.
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