About: Induced Thermolysis of tert-Butyl Phenylperacetates byThiophenol: Simultaneous Occurrence of Homolysis and SingleElectron Transfer

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/w
Subject	Article
Title	Induced Thermolysis of tert-Butyl Phenylperacetates byThiophenol: Simultaneous Occurrence of Homolysis and SingleElectron Transfer
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/101021jo0106290/m/print http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/101021jo0106290/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/101021jo0106290/authorship/3 http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/101021jo0106290/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_23/101021jo0106290/authorship/2
Author	Kim Chun Soo Tuchkin Alexey Kim Sung Soo
Abstract	Thermolysis of tert-butyl phenylperacetates in the presence of thiophenol takes place via dualmechanism. The two-bond homolysis indicates= −1.16, testifying to polar transition states.The single electron transfer yields a radical anion intermediate which undergoes fragmentationwith ρET = 1.01.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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