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À propos de : The Particular Sensitivity of Silyl Ethers of d-Glucal toward TwoVilsmeier−Haack Reagents POCl3·DMF and (CF3SO2)2Ο·DMF.Their Unique and Selective Conversion to the CorrespondingC(6)-O-Formates        

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  • The Particular Sensitivity of Silyl Ethers of d-Glucal toward TwoVilsmeier−Haack Reagents POCl3·DMF and (CF3SO2)2Ο·DMF.Their Unique and Selective Conversion to the CorrespondingC(6)-O-Formates
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  • The two electrophilic Vilsmeier−Haack reagents POCl3·DMF 2 or (CF3SO2)2Ο·DMF 3 mediate theone-step and selective conversion of O-triethylsilyl (O-TES), O-tert-butyldimethylsilyl (O-TBDMS),O-tert-butyldiphenylsilyl (O-TBDPS), and O-triisopropylsilyl (O-TIPS) ethers of d-glucal to thecorresponding C(6)-O-formates.
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