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| - A Highly Convergent Synthesis of a Complex OligosaccharideDerived from Group B Type III Streptococcus
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| - An efficient synthesis of a heptasaccharide derived from group B type III Streptococcus carryingan artificial spacer (1) is described. Rapid assembly of a protected heptasaccharide (16a) isaccomplished from readily available building blocks 2−5 without a single protecting groupmanipulation between glycosylation steps. The synthetic strategy may be applied to the assemblyof other branched complex oligosaccharides. The deprotected heptasaccharide 1 was coupled to apoly[N-(acryloyloxy)succinimide, and the resulting material will be used for the development of anELISA assay to detect antibodies against GBS, type III in pregnant women.
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