About: Novel Sparteine-Mediated Enantio-Dichotomic Formal Synthesisof (R)-(−)- and (S)-(+)-Curcuphenol

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_8/w
Subject	Article
Title	Novel Sparteine-Mediated Enantio-Dichotomic Formal Synthesisof (R)-(−)- and (S)-(+)-Curcuphenol
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_8/101021jo001485c/m/web http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_8/101021jo001485c/m/print
related by	http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_8/101021jo001485c/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2001/volume_66/issue_8/101021jo001485c/authorship/2
Author	Takemoto Yoshiji Kimachi Tetsutaro
Abstract	High and opposite enantiodiscriminations were observed between tertiary amides and secondaryamides in the sparteine-mediated lateral metalation−allylation of 2-ethyl-m-toluamide derivatives(2a, 2e). The results described above have been applied for the formal synthesis of both enantiomersof curcuphenol. The brief mechanistic studies suggested that stereoinformation was introducedafter the deprotonation step.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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