About: Proline-Catalyzed One-Step AsymmetricSynthesis of 5-Hydroxy-(2E)-hexenal fromAcetaldehyde

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/w
Subject	Note
Title	Proline-Catalyzed One-Step AsymmetricSynthesis of 5-Hydroxy-(2E)-hexenal fromAcetaldehyde
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo015881m/m/print http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo015881m/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo015881m/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo015881m/authorship/3 http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo015881m/authorship/2
Author	Barbas Carlos F. Notz Wolfgang http://www.idref.fr/080129722/id
Abstract	For the first time, the l-proline-catalyzed directasymmetric self-aldolization of acetaldehyde is describedaffording (+)-(5S)-hydroxy-(2E)-hexenal 2 with ee's rangingfrom 57 to 90%. Further transformations of 2 into synthetically valuable building blocks are presented. A mechanismfor the formation of 2 is proposed.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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