About: Direct Conversion of Bromohydrins toKetones by a Free Radical Elimination ofHydrogen Bromide1

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/w
Subject	Note
Title	Direct Conversion of Bromohydrins toKetones by a Free Radical Elimination ofHydrogen Bromide1
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo016113y/m/print http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo016113y/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo016113y/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_1/101021jo016113y/authorship/2
Author	Dolenc Darko Harej Maja
Abstract	Secondary β-bromo alcohols can be transformeddirectly to ketones in very good yields by a free radicalprocess. Tertiary β-bromo alcohols do not react while theprimary ones are transformed to aldehydes in lower yields.The reaction involves an abstraction of a hydrogen atom αto an OH group, followed by elimination of the bromine atomand subsequent tautomerization of an enol to a ketone.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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