Documentation scienceplus.abes.fr version Bêta

À propos de : Photocycloaddition of Four-Carbon-Tethered Pyridones.Intramolecular Hydrogen Bonding and Facilitated AmideHydrolysis by a Proximal Secondary Alcohol1        

AttributsValeurs
type
Is Part Of
Subject
Title
  • Photocycloaddition of Four-Carbon-Tethered Pyridones.Intramolecular Hydrogen Bonding and Facilitated AmideHydrolysis by a Proximal Secondary Alcohol1
has manifestation of work
related by
Author
Abstract
  • Four-carbon-tethered pyridones undergo photocycloaddition to give exclusively trans-[4 + 4]products. The presence of a tether alcohol engenders a solvent-dependent diastereoselectivity forthe cycloaddition by intramolecular hydrogen bonding to the adjacent pyridone. Followingcycloaddition, the alcohol can deliver a carbonyl group to the proximal, hindered amide nitrogen,leading to a very facile amide hydrolysis.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata