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À propos de : Generation of 1-Azapentadienyl Anion fromN-(tert-Butyldimethylsilyl)-3-buten-1-amine        

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  • Generation of 1-Azapentadienyl Anion fromN-(tert-Butyldimethylsilyl)-3-buten-1-amine
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  • N-(tert-Butyldimethylsilyl)-3-buten-1-amine undergoes allylic deprotonation at the 2-position when exposedto 2 equiv of nBuLi in THF. This allylic anion undergoeslithium hydride elimination to generate a 1-azapentadienylanion. The anion is generated cleanly and completely.
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