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À propos de : Synthesis of Aliphatic Ketones from AllylicAlcohols through ConsecutiveIsomerization and Chelation-AssistedHydroacylation by a Rhodium Catalyst        

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  • Synthesis of Aliphatic Ketones from AllylicAlcohols through ConsecutiveIsomerization and Chelation-AssistedHydroacylation by a Rhodium Catalyst
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  • An allylic alcohol, utilized as a precursor for analiphatic aldehyde, reacted with olefins to afford aliphaticketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline,aniline, and benzoic acid through a tandem reaction of anisomerization and a chelation-assisted hydroacylation.
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