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À propos de : Oxidative Carbomethoxylation of AlkenesUsing a Pd(II)/Molybdovanadophosphate(NPMoV) System under Carbon Monoxideand Air        

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  • Oxidative Carbomethoxylation of AlkenesUsing a Pd(II)/Molybdovanadophosphate(NPMoV) System under Carbon Monoxideand Air
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  • Oxidative carbomethoxylation of cyclopentene (1)under carbon monoxide and air by the use of a catalyticamount of Pd(OAc)2 and molybdovanadophosphate (NPMoV)led to dimethyl cis-1,2-cyclopentanedicarboxylate (2) anddimethyl cis-1,3-cyclopentanedicarboxylate (3) in good yields.Total yields of 2 and 3 were found to be improved by addinga small amount of NH4Cl. Several alkenes were similarlyconverted into the corresponding dimethyl dicarboxylates.The role of Cl- in the present catalytic system is suggested.
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