About: One-Step Conversion of Alcohols intoNitriles with Simultaneous Two-CarbonChain Elongation.(Cyanomethyl)trimethylphosphoniumIodide as a Reagent with a Dual Mode ofAction

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_14/w
Subject	Note
Title	One-Step Conversion of Alcohols intoNitriles with Simultaneous Two-CarbonChain Elongation.(Cyanomethyl)trimethylphosphoniumIodide as a Reagent with a Dual Mode ofAction
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_14/101021jo025731r/m/print http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_14/101021jo025731r/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_14/101021jo025731r/authorship/1
Author	Zaragoza Florencio
Abstract	Treatment of alcohols with an excess of (cyanomethyl)trimethylphosphonium iodide leads, after aqueoushydrolysis, to the clean formation of nitriles with two morecarbon atoms than present in the original alcohol. Benzylic,allylic, and aliphatic alcohols without β-branching (RCH2CH2OH) have been converted to nitriles with success. Therequired phosphonium iodide is simple to prepare and canbe stored for a long time at room temperature.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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