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| - Highly Sulfurated Heterocycles via Dithiiranes and Trithietanesas Key Intermediates
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| - 2,2,4,4-Tetramethyl-3-thioxocyclobutanone (8b) easily reacts with gaseous chlorine to yield the stableα-chloro sulfenyl chloride 10. The same product was obtained when 8b was treated either withphosphorus pentachloride (PCl5) or sulfuryl chloride (SO2Cl2) in CCl4 solution. Sulfur dichloride(SCl2) reacts with 8b to give the α-chloro thiosulfenyl chloride 12 along with an almost equimolaramount of the trisulfide 13b. The less reactive disulfur dichloride (S2Cl2) was shown to react slowlywith 8b and the symmetrical tetrasulfide 15 was found as the exclusive product. The purethiosulfenyl chloride 12 added to adamantanethione (8c) yielded the unsymmetrical trisulfide 13c.When 12 was treated with thioacetic acid, the acetylated trisulfide 17 was formed in high yield.“Unzipping” reactions with the acetylated disulfide 16 and trisulfide 17 with morpholine in THFat −40 °C led to the formation of mixtures of two sulfur-rich heterocycles identified as thepentathiepane 6b and the hexathiepane 7b. A mixture of analogous products was obtained whenα-chloro sulfenyl chloride 10 was treated with sodium sulfide in anhydrous THF at −40 °C. Theformation of 6b and 7b is believed to occur via the intermediate dithiirane 1b and/or the isomericthiosulfine 2b. In the case of 17 the reaction starts probably with the formation of a nonisolabletetrathiane 18b as presented in Scheme .
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