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À propos de : Hydroformylation of Alkenes EmployingRhodium(I) Complexes and a PhosphineOxide Ligand        

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  • Hydroformylation of Alkenes EmployingRhodium(I) Complexes and a PhosphineOxide Ligand
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  • Following the facile synthesis of a novel phosphine oxide compound, (diphenylphosphinoyl)phenylmethanol(1), this compound was employed as a ligand in the rhodium-catalyzed hydroformylation of alkenes, with good conversionsand regioselectivities. This ligand was partially resolvedusing an enzyme, and enantioselective hydroformylation wascarried out with the addition of a rhodium(I) complex. Therhodium(I) complex containing ligand 1 was not isolated,although it was subjected to low-temperature NMR studies.
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