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À propos de : Synthesis and Properties of a New Memberof the Calixnaphthalene Family: AC2-Symmetrical endo-Calix[4]naphthalene        

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  • Synthesis and Properties of a New Memberof the Calixnaphthalene Family: AC2-Symmetrical endo-Calix[4]naphthalene
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  • The synthesis of a new endo-calix[4]naphthaleneis described. The reaction sequence involves the cyclocondensation of a key bisnaphthylmethane intermediate (8)with formaldehyde. This key intermediate (8) is formedusing a modified Suzuki−Miyaura Pd-catalyzed cross-coupling reaction between bromomethylnaphthyl (6) andnaphthylboronic acid (7), both of which can be derived from2-hydroxynaphthoic acid.
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