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À propos de : Easy Access to N,N-Bis(but-3-enyl)-,N-Allyl-N-(but-3-enyl)-, andN-(But-3-ynyl)-N-(but-3-enyl)-amines        

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  • Easy Access to N,N-Bis(but-3-enyl)-,N-Allyl-N-(but-3-enyl)-, andN-(But-3-ynyl)-N-(but-3-enyl)-amines
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  • N,N-Bis(but-3-enyl)amines 5a−i were preparedin overall 74% yield from 1-(triphenylphosphoroylideneaminoalkyl)benzotriazole using an aza-Wittig reaction withaldehydes followed by a double Grignard reaction withallylmagnesium bromide. Use of vinyl or 1-propynylmagnesium bromide and allylmagnesium bromide in a sequentialfashion also formed the expected doubly unsaturated amines9a,b and 12, respectively.
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