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À propos de : Ru3(CO)12-Catalyzed C−H/CO/OlefinCoupling of N-Pyridylindolines. DirectCarbonylation at a C−H Bond δ to thePyridine Nitrogen        

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  • Ru3(CO)12-Catalyzed C−H/CO/OlefinCoupling of N-Pyridylindolines. DirectCarbonylation at a C−H Bond δ to thePyridine Nitrogen
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  • The reaction of N-pyridylindolines with CO andethylene in the presence of Ru3(CO)12 results in directcarbonylation at a C−H bond δ to the pyridine sp2 nitrogen,which represents a new type of C−H/CO/olefin coupling. Thepresence of a pyridine ring as a directing group on thesubstrates is essential for the reaction to proceed. The choiceof N,N-dimethylacetamide (DMA) as the solvent is crucialfor the reaction to proceed efficiently.
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