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À propos de : Stereoselective Synthesis ofNeu5Acα(2→5)Neu5Gc: The Building Blockof Oligo/Poly(→5-OglycolylNeu5Gcα2→)Chains in Sea Urchin Egg Cell SurfaceGlycoprotein        

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  • Stereoselective Synthesis ofNeu5Acα(2→5)Neu5Gc: The Building Blockof Oligo/Poly(→5-OglycolylNeu5Gcα2→)Chains in Sea Urchin Egg Cell SurfaceGlycoprotein
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  • The synthesis of a sialic acid dimer derivative,Neu5Acα(2→5)Neu5Gc, is described. The synthetic strategyis based on the use of allyl alcohol to achieve an exclusiveα-sialylation product. The allyloxy group is also a latentglycolic acid that provides the subsequent coupling withneuraminate with minimal protection−deprotection manipulations.
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