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Friedel−Crafts Type Reaction of Ferrocenewith β-Ketoesters
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http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/w
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Title
Friedel−Crafts Type Reaction of Ferrocenewith β-Ketoesters
has manifestation of work
http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/101021jo025717e/m/web
http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/101021jo025717e/m/print
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http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/101021jo025717e/authorship/2
http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/101021jo025717e/authorship/1
Author
Plazuk Damian
http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_24/101021jo025717e/zakrzewskijanusz
Abstract
The reaction of ferrocene with β-ketoesters in thepresence of BF3·Et2O or CF3SO3H affords β-ferrocenyl-α,β-unsaturated esters in 56−83% yield. In the case of α-unsubstituted-β-ketoesters the reaction is totally E-stereoselective.
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The Journal of Organic Chemistry
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