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À propos de : Highly Stereoselective Syntheses of syn- and anti-1,2-AminoAlcohols        

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  • Highly Stereoselective Syntheses of syn- and anti-1,2-AminoAlcohols
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  • The reduction of N-protected amino ketones can be carried stereoselectively to produce either thesyn- or anti-amino alcohol diastereomer. Carbamate-protected amino ketones can be reducedpredictably and selectively to anti-amino alcohols with LiAlH(O-t-Bu)3 in ethanol at −78 °C. N-Trityl-protected amino ketones can be reduced selectively to syn-amino alcohols with LiAlH(O-t-Bu)3 inTHF at −5 °C.
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