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À propos de : Structure−Reactivity Correlation of Anilines in Acetic Acid        

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  • Structure−Reactivity Correlation of Anilines in Acetic Acid
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  • The oxidation of aniline in glacial acetic acid with percarbonate, a dry carrier of hydrogen peroxide,is a second-order reaction conforming to the isokinetic relationship. The hitherto followed methodof correlation of the reaction rates in terms of the structure−reactivity relationships is unsatisfactoryand erroneous. But the reaction rates of molecular anilines, obtained for the first time, conform tothe structure−reactivity relationships.
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