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À propos de : Electrogenerated Base-InducedN-Acylation of Chiral Oxazolidin-2-ones. 21        

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  • Electrogenerated Base-InducedN-Acylation of Chiral Oxazolidin-2-ones. 21
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  • An improved and efficient electrochemical N-acylation of chiral oxazolidin-2-ones has been achieved. Thegeneration of the nitrogen anion is obtained under mildconditions and without addition of base or probase, by directelectrolysis of a solution of MeCN−TEAP containing theoxazolidinone. Acylation agents (acid chlorides or anhydrides) were added at the end of the electrolysis. N-Acylatedproducts were isolated in high to excellent yields.
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