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[3 + 2] Annulation of β-Heteroatom-Substituted α,β-UnsaturatedAcylsilanes with Methyl Ketone Enolates: Scope and Investigationof the Reaction Course
Highly Efficient B(C6F5)3-Catalyzed Hydrosilylation of Olefins
Cp*2TiMe2: An Improved Catalyst for theIntermolecular Addition of n-Alkyl- andBenzylamines to Alkynes
Remarkable Diastereoselectivity in the Addition of Allylic andUnsaturated Diorganozinc Reagents toβ-(N,N-Dialkylamino)-aldehydes
Transmetalation of Palladium Enolate andIts Application in Palladium-CatalyzedHomocoupling of Alkynes: A Room-Temperature, Highly EfficientRoute To Make Diynes
Acid−Base Equilibria in Nonpolar Media. 2. Self-ConsistentBasicity Scale in THF Solution Ranging from 2-Methoxypyridineto EtP1(pyrr) Phosphazene
Polyfluoroether Derivatives via Nucleophilic Fluorination ofGlyoxal Hydrates with Deoxofluor
A Novel Photochemical Reaction of 2-Alkoxynicotinates toCage-Type Photodimers
Gas-Phase Identity Nucleophilic Substitution Reactions ofCyclopropenyl Halides
An Approach to the Stereoselective Synthesis of syn- andanti-1,3-Diol Derivatives. Retention of Configuration in theMitsunobu Reaction
Protease-Mediated Fragmentation of p-Amidobenzyl Ethers: ANew Strategy for the Activation of Anticancer Prodrugs
Synthesis of Aza Polycyclic Compounds Derived from Pyrrolidine,Indolizidine, and Indole via Intramolecular Diels−AlderCycloadditions of Neutral 2-Azadienes
The Preorganization Step in Organic Reaction Mechanisms.Charge-Transfer Complexes as Precursors to ElectrophilicAromatic Substitutions
Kulokekahilide-1, a Cytotoxic Depsipeptide from theCephalaspidean Mollusk Philinopsis speciosa
Ab Initio and Experimental Studies on the Hetero-Diels−Alderand Cheletropic Additions of Sulfur Dioxide to(E)-1-Methoxybutadiene: A Mechanism Involving Three Moleculesof SO2
Synthesis and Structural Characterization of Cis- andTrans-Fused 4a,5,6,7,8,8a-Hexahydro-2H,4H-1,3-benzodithiines andTheir 2-Methyl and 2,2-Dimethyl Derivatives
Elongation and Contraction of Molecular Springs. Synthesis,Structures, and Properties of Bridged [7]Thiaheterohelicenes
2-Trimethylsilylethyl Sulfides in the von Braun CyanogenBromide Reaction: Selective Preparation of Thiocyanates andApplication to Nucleoside Chemistry
A Novel Free-Radical Ring Contraction of aCyclic Carbamate
Theoretical and Experimental Studies of Biotin Analogues ThatBind Almost as Tightly to Streptavidin as Biotin
Diphenyl Disulfide and Sodium in NMP as an Efficient Protocolfor in Situ Generation of Thiophenolate Anion: SelectiveDeprotection of Aryl Alkyl Ethers and Alkyl/Aryl Esters underNonhydrolytic Conditions,
Five- and Six-Membered Ring Opening of PyroglutamicDiketopiperazine
Concise Syntheses of Nonracemic γ-Fluoroalkylated AllylicAlcohols and Amines Via an Enantiospecific Palladium-CatalyzedAllylic Substitution Reaction
Asymmetric Synthesis of Axially Chiral Benzamides and Anilidesby Enantiotopic Lithiation of Prochiral Arene ChromiumComplexes
Electrochemical Homocoupling of 2-BromomethylpyridinesCatalyzed by Nickel Complexes
Mechanistic Study of the Mitsunobu Reaction
Accurate Calculation of Aromaticity ofBenzene and Antiaromaticity ofCyclobutadiene: New HomodesmoticReactions
Azidolysis of α,β-Epoxycarboxylic Acids. A Water-Promoted Process Efficiently Catalyzed by Indium Trichlorideat pH 4.0
Free-Radical-Mediated Conjugate Additions. EnantioselectiveSynthesis of Butyrolactone Natural Products: (−)-Enterolactone,(−)-Arctigenin, (−)-Isoarctigenin, (−)-Nephrosteranic Acid, and(−)-Roccellaric Acid
A New Type of Ionophore Family Utilizing the Cation-Olefinic πInteraction: Theoretical Study of [n]Beltenes
Directing Abilities of Alcohol-Derived Functional Groups in theHydroformylation of Olefins
Metal-Mediated Carbonyl-1,3-butadien-2-ylation by1,4-Bis(methanesulfonyl)-2-butyne or 1,4-Dibromo-2-butyne inAqueous Media: Asymmetric Synthesis of 3-Substituted3-Hydroxy-β-lactams
Combining Lipase-Catalyzed Enantiomer-Selective Acylation withFluorous Phase Labeling: A New Method for the Resolution ofRacemic Alcohols
Enantiomerically Pure α-Amino Acid Synthesis viaHydroboration−Suzuki Cross-Coupling
Stereodefined Synthesis of O3‘-Labeled Uracil Nucleosides.3‘-[17O]-2‘-Azido-2‘-deoxyuridine 5‘-Diphosphate as a Probe for theMechanism of Inactivation of Ribonucleotide Reductases
The Hydrogen Bonding and Hydration of 2‘-OH in Adenosine andAdenosine 3‘-Ethyl Phosphate
Synthesis of 2,3-Disubstituted Benzo[b]thiophenes viaPalladium-Catalyzed Coupling and Electrophilic Cyclization ofTerminal Acetylenes
From a Biogenetic Scenario to a Synthesis of the ABC Ring ofManzamine A
The Reaction of Fullerene C60 with 4,6-Dimethyl-1,2,3-triazine: Formation of an Open-Cage Fullerene Derivative.
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