About: A Preliminary Approach to Nonenolizableβ,β-Tricarbonyls: Assembly of aHyperevolutin Prototype1

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_9/w
Subject	Note
Title	A Preliminary Approach to Nonenolizableβ,β-Tricarbonyls: Assembly of aHyperevolutin Prototype1
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_9/101021jo010884k/m/print http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_9/101021jo010884k/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_9/101021jo010884k/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2002/volume_67/issue_9/101021jo010884k/authorship/2
Author	Young David G. J. Zeng Dongxiang
Abstract	A synthetic approach to the hyperevolutin Aacylated phloroglucinol ring system is described. Thus,intramolecular allene−nitrile oxide cycloaddition of 10 wasused to construct the bicyclic framework and vicinal quaternary centers in cycloadduct 20 in the key bond-formingstep. Treatment of 20 with Raney nickel and hydrogen gasproduced primary enamine 21 which contains a nonenolizable β,β-tricarbonyl group in latent form.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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