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À propos de : A Phosphine-Catalyzed [3+2] CycloadditionStrategy Leading to the First TotalSynthesis of (−)-Hinesol        

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  • A Phosphine-Catalyzed [3+2] CycloadditionStrategy Leading to the First TotalSynthesis of (−)-Hinesol
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  • In one step, the skeleton of cis-spirovetivanes wasconstructed with high stereoselectivity by the phosphine-catalyzed [3+2] cycloaddition reaction of tert-butyl 2,3-butadienoate or 2-butynoate with 3-methyl-2-methylenecyclohexanone (5). This method was exemplified by the firsthighly efficient total synthesis of natural product (−)-hinesol,which is an active ingredient of cerebral circulation andmetabolism improvers.
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