Documentation scienceplus.abes.fr version Bêta

À propos de : Stereoselective Synthesis of the Nonproteinogenic Amino Acid(2S,3R)-3-Amino-2-hydroxydecanoic Acid from(4S,5S)-4-Formyl-5-vinyl-2-oxazolidinone        

AttributsValeurs
type
Is Part Of
Subject
Title
  • Stereoselective Synthesis of the Nonproteinogenic Amino Acid(2S,3R)-3-Amino-2-hydroxydecanoic Acid from(4S,5S)-4-Formyl-5-vinyl-2-oxazolidinone
has manifestation of work
related by
Author
Abstract
  • (4S,5S)-4-Formyl-5-vinyl-2-oxazolidinone (4b), which is readily obtained via a zinc−silver-mediatedreductive elimination of α-d-lyxofuranosyl phenyl sulfone (3b), is successfully converted to thenaturally occurring, nonproteinogenic amino acid (2S,3R)-3-amino-2-hydroxydecanoic acid (2). Alsoin this study, a facile “oxazolidinone rearrangement” reaction is uncovered during the attemptedformation of the (methylthio)thiocarbonate derivative of the oxazolidinone alcohol 7.
article type
is part of this journal



Alternative Linked Data Documents: ODE     Content Formats:       RDF       ODATA       Microdata