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À propos de : Bent Structure and Dynamic Stereochemistry of ChiralAcridinium Cations        

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  • Bent Structure and Dynamic Stereochemistry of ChiralAcridinium Cations
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  • Chiral acridinium cations, easily prepared by reaction of enantiopure primary amines and tris(2,6-dimethoxy)trityl cation, display restricted rotations around the C(sp3)−N(sp2) bond. A bendingof the aromatic backbone and “out-of-plane” displacements of C(9) and N(10) atoms are enforced ifbulky amines are introduced.
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