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À propos de : Novel Synthesis of 2-Oxo-3-butynoates byCopper-Catalyzed Cross-Coupling Reactionof Terminal Alkynes and MonooxalylChloride        

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  • Novel Synthesis of 2-Oxo-3-butynoates byCopper-Catalyzed Cross-Coupling Reactionof Terminal Alkynes and MonooxalylChloride
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  • A general and efficient Cu(I)-catalyzed cross-coupling reaction of terminal alkynes and monooxalyl chloride for the synthesis of 2-oxo-3-butynoates and 2-oxo-3-butynoamides was developed. Readily available startingmaterials, the mild reaction conditions, wide functionalgroup tolerance, and the obviation of stoichiometric organolithium or magnesium reagents combine to highlight thisreaction.
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