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À propos de : Synthesis of 4-Deoxy-l-(and d-)hexoses from ChiralNoncarbohydrate Building Blocks        

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  • Synthesis of 4-Deoxy-l-(and d-)hexoses from ChiralNoncarbohydrate Building Blocks
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  • 4-Deoxy-l-hexoses were synthesized starting from our previously reported reagent 1 and (R)-benzylglycidyl ether, which led in few steps to a substituted dihydropyran 6. The stereocontrolledhydroxylation of the latter afforded the corresponding 4-deoxy-l-hexoses 7a, 9, and 11. The sameprocedure, starting from (S)-benzyl glycidyl ether, enabled the preparation of their d-seriesenantiomers.
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