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Effect of Double-Hyperconjugation on the Apparent Donor Abilityof σ-Bonds: Insights from the Relative Stability of δ-SubstitutedCyclohexyl Cations
A New Polymer-Supported Reagent for theSynthesis of β-Lactams in Solution
Studies on the Total Synthesis of (−)-CP-263,114
Phase Transfer Catalysis (PTC)Sulfanylation of Some2-Methylsulfinyl-Cyclanones
Design, Synthesis, and Photochemical Behavior of Poly(benzylester) Dendrimers with Azobenzene Groups throughout TheirArchitecture
Decomposition of Alkene Adducts of Thianthrene Cation Radicalin Nitrile Solvents. Formation of Alkyl-2-oxazolines and a NewClass of Four-Component Products: 5-[(1-Alkoxyalkylidene)ammonio]alkylthianthreniumDiperchlorates
P(i-BuNCH2CH2)3N: An Effective Ligand in thePalladium-Catalyzed Amination of Aryl Bromides and Iodides
Enhanced Methylation Rate within a Foldable Molecular Receptor
Highly Stereoselective Grignard Addition to Cis-SubstitutedC-Cyclopropylaldonitrones. The Bisected s-Trans Transition StateCan Be Stabilized Effectively by the Lewis Acid-Coordination
Synthesis of Optically Active Constrained 2-SubstitutedNorstatines: A Straightforward Application of Seebach's “SRS”Synthetic Principle
Bis(dialkylamide)hydrogen Dibromobromate Precursors ofHypobromite Ion in Reactions with Nerve and Blister AgentSimulants
A New Structural Theme in the Imidazole-Containing Alkaloidsfrom a Calcareous Leucetta Sponge
A Mechanistic Study of the Alkaline Hydrolysis of Diaryl SulfateDiesters
Al-Isopropoxydiisobutylalane: A Study ofthe Effect of Solvent on the Rate andStereoselectivity of Cyclic KetoneReduction
Scope and Limitations of Pd2(dba)3/P(i-BuNCH2CH2)3N-CatalyzedBuchwald−Hartwig Amination Reactions of Aryl Chlorides
Dimerization of Butenolide Structures. A Biomimetic Approach tothe Dimeric Sesquiterpene Lactones (±)-Biatractylolide and(±)-Biepiasterolide
Rearrangement ofSpiroacetals of the 1,6-Dioxaspiro[4.5]decan-10-yl Methanesulfonate Type. Synthesis of cis-Fused 1,6-Dioxadecalins.
First Synthesis of rac-(5-2H3)-α-CEHC, aLabeled Analogue of a Major Vitamin EMetabolite
Direct Oxidative Cleavage of α- andβ-Dicarbonyls and α-Hydroxyketones toDiesters with KHSO5
Impact of Azaproline on Peptide Conformation
Correlating Acidities, Electron Affinities, and Bond DissociationEnergies. Measure One, Get All Three!
Ruthenium- and Enzyme-Catalyzed Dynamic Kinetic AsymmetricTransformation of 1,4-Diols: Synthesis of γ-Hydroxy Ketones
Stereoselective Synthesis ofPentacarbonyl(3-oxa-2-bicyclo[3.1.0]hexylidene)- andPentacarbonyl(cyclopropylmethoxymethylene)tungstenCompounds on the Route to Cyclopropane-γ-lactones and-carboxylates
Synthesis and Reactivity of Some6-Substituted-2,4-dimethyl-3-pyridinols, a Novel Class ofChain-Breaking Antioxidants
Concise Synthesis of Novel Practical Sulfamide−Amine Alcoholsfor the Enantioselective Addition of Diethylzinc to Aldehydes
Cocyclotrimerization of 6-Alkynylpurines with α,ω-Diynes as aNovel Approach to Biologically Active 6-Arylpurines
Total Syntheses of Epothilones B and D
Application of a New Bicyclic Triaminophosphine Ligand in Pd-Catalyzed Buchwald-Hartwig Amination Reactions of Aryl Chlorides, Bromides, and Iodides.
Assembly and Characterization of Novel Hydrogen-Bond-InducedNanoscale Rods
Reactions of Substituted (Methylthio)benzylidene Meldrum's Acidswith Secondary Alicyclic Amines in Aqueous DMSO. Evidence forRate-Limiting Proton Transfer
Total Synthesis of the Kopsia lapidilecta Alkaloid(±)-Lapidilectine B
Increased Enantioselectivity in the Addition of Diethylzinc to Benzaldehyde bythe Use of Chiral Ligands Containing the α-PhenylethylaminoGroup in Combination with Achiral Ligands.
Mechanism of the Oxidation of Sulfides by Dioxiranes: Conformational Mobility and Transannular Interaction in theOxidation of Thianthrene 5-Oxide
Synthesis of Nα-(1-Phenyl-2-mercaptoethyl) Amino Acids, NewBuilding Blocks for Ligation and Cyclization at Non-CysteineSites: Scope and Limitations in Peptide Synthesis
Salt Effects on the Conformational Behavior of 5-Carboxy- and5-Hydroxy-1,3-dioxane1
NaNO2-Mediated Transformation of Aliphatic SecondaryNitroalkanes into Ketones or Oximes under Neutral, AqueousConditions: How the Nitro Derivative Catalyzes Its OwnTransformation
Synthesis and Characterization ofDibenzodioxadiselenafulvalene
Benzhydryl as an Efficient SelectiveNitrogen Protecting Group for Uracils
Tuning the Acceptors in Catalyzed Cyclizations Initiated byAllenes. Silylstannylation/Cyclization of Allene-Aldehydes forSynthesis of Polyalkylated Indolizidines Including 223ACongeners
Bismuth Triflate-CatalyzedThree-Component Mannich-Type Reaction
Solvolytic Ring-Opening Reactions of Cyclopropyl Bromides. AnAssessment of the Woodward−Hoffmann−DePuy Rule
Synthesis and Relative Stability of3,5-Diacyl-4,5-dihydro-1H-pyrazoles Prepared by DipolarCycloaddition of Enones and α-Diazoketones
Studies on the Base-Promoted Conversion of Conjugated AlkynylEsters to α-Substituted α-Allenyl Esters
Stereoselective Synthesis ofAllyl-C-mannosyl Compounds: Use of a Temporary SiliconConnection in Intramolecular Allylation Strategies with Allylsilanes.
Catalytic Asymmetric Reactions for Organic Synthesis: TheCombined C−H Activation/Siloxy-Cope Rearrangement
Kinetics and Mechanism of the Aminolysis of Aryl N-EthylThiocarbamates in Acetonitrile
Domino “[3+3]-Cyclization-Homo-Michael” Reactions of 1,3-BissilylEnol Ethers with 1,1-Diacylcyclopropanes
Novel Synthesis of Bicycles with FusedPyrrole, Indole, Oxazole, and ImidazoleRings
New Synthesis, Properties, and Oxidizing Ability of1,3-Dimethyl-5,10-methanocycloundeca[4,5]furo[2,3-d]pyrimidin-2,4(1,3H)-dionylium Tetrafluoroborate
Improved Straightforward ChemicalSynthesis of Dihydroxyacetone Phosphatethrough Enzymatic Desymmetrization of2,2-Dimethoxypropane-1,3-diol
Enantioselective [4 + 2] Cycloadditions of o-Quinone Methides: Total Synthesis of (+)-Mimosifoliol and Formal Synthesis of(+)-Tolterodine
Design and Synthesis of Dimeric Heparinoid Mimetics
Synthesis and Characterization of a Cobalamin−ColchicineConjugate as a Novel Tumor-Targeted Cytotoxin
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