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À propos de : Organosoluble Copper Clusters as Precatalysts forCarbon−Heteroelement Bond-Forming Reactions: Microwave andConventional Heating        

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  • Organosoluble Copper Clusters as Precatalysts forCarbon−Heteroelement Bond-Forming Reactions: Microwave andConventional Heating
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  • The coupling of aryl iodides with alcohols under mild conditions has been explored using self-assembled octanuclear copper clusters as catalysts. Reactions involving tetrahydrofurfuryl alcoholwere typically complete in 4−8 h at 110 °C using an oil bath or 1−3 h with microwave heating.High yields of alkyl aryl ethers were obtained with catalyst loadings as low as 0.4 mol % cluster.
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