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À propos de : A [5]HELOL Analogue That Senses Remote Chirality in Alcohols,Phenols, Amines, and Carboxylic Acids        

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  • A [5]HELOL Analogue That Senses Remote Chirality in Alcohols,Phenols, Amines, and Carboxylic Acids
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  • A route is developed to a structural analogue of [5]HELOL, a previously reported helically groovedsensor of remote chirality. It gives the material enantiomerically pure and in multigram quantities.The enantiomers of alcohols, phenols, amines, and carboxylic acids, even when their centers ofchirality are remote from any functional groups, can be differentiated by 31P NMR spectroscopicanalyses of their reaction products with the chlorophosphite of this material.
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