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À propos de : Highly Stereoselective Synthesis, Structure, and Application of(E)-9-[2-(Silyl)ethenyl]-9H-carbazoles        

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  • Highly Stereoselective Synthesis, Structure, and Application of(E)-9-[2-(Silyl)ethenyl]-9H-carbazoles
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  • (E)-N-(Silyl)vinylcarbazole has been easily prepared via a new catalytic route, silylative coupling(SC) of vinylcarbazole with vinyltrisubstituted silanes catalyzed by [RuH(Cl)(CO)(PCy3)2]. X-raystructures of two silylvinylcarbazoles as first N-vinylcarbazole derivatives have been resolved. ThePd-catalyzed Hiyama coupling reaction (also as the tandem reaction with SC) of synthesized (E)-N-(triethoxysilyl)vinylcarbazole with iodobenzene has been performed to afford (E)-N-(phenylvinyl)carbazole with high yield and stereoselectivity.
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