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À propos de : A Model Study toward the Total Synthesis ofN-Deacetyllappaconitine        

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  • A Model Study toward the Total Synthesis ofN-Deacetyllappaconitine
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  • A model study leading to the preparation of the AEF rings of N-deacetyllappaconitine is described.The conjugate addition to the α-alkyl cyclohexenone 10 proceeded with high diastereocontrol. TheMannich cyclization of 16 to 4 was accomplished by heating with Rexyn-300 and Na2SO4.
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