About: Preparation and Synthetic Application of a Novel Ketene SilylAcetal of Methyl Trifluoropyruvate

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/w
Subject	Article
Title	Preparation and Synthetic Application of a Novel Ketene SilylAcetal of Methyl Trifluoropyruvate
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/101021jo051242q/m/print http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/101021jo051242q/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/101021jo051242q/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/101021jo051242q/authorship/2 http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_22/101021jo051242q/authorship/3
Author	Uneyama Kenji Katagiri Toshimasa Takikawa Go
Abstract	A novel trifluoromethyl ketene silyl acetal (4) of methyl trifluoropyruvate (1) was prepared in 82%yield by metal Mg reduction in a (TMS)Cl/THF system. Subsequent carbon−carbon bond formationsuch as Mukaiyama aldol, Michael addition, and other nucleophilic reactions of 4 at thetrifluoromethylated carbon with various electrophiles gave various coupling products in high yields.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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