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À propos de : A Convenient Oxazole C-2 ProtectingGroup: The Synthesis of 4- and5-Substituted Oxazoles via Metalation of2-Triisopropylsilyloxazoles        

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  • A Convenient Oxazole C-2 ProtectingGroup: The Synthesis of 4- and5-Substituted Oxazoles via Metalation of2-Triisopropylsilyloxazoles
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  • Metalation of oxazoles at the 4 and 5 position was achievedafter regioselective C-2 silyl protection. Removal of theprotecting group was then accomplished under mild conditions allowing for a straightforward preparation of C-5monosubstituted and C-4,5 disubstituted oxazoles. The firstpractical C-2 protecting group of oxazoles has been demonstrated.
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