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À propos de : Arene−Chromium Tricarbonyl Complexesin the Pauson−Khand Reaction        

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  • Arene−Chromium Tricarbonyl Complexesin the Pauson−Khand Reaction
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  • We show the use of arene−chromium tricarbonyl complexesin intra- and intermolecular Pauson−Khand reactions. Bothstyrene and ethynylbenzene complexes react with alkynesand olefins. The synthesis of enynes connected throughchromium-complexed aromatic rings is developed. The intramolecular Pauson−Khand reaction occurs in a totallydiastereoselective manner.
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