| Abstract
| - Irradiation of isoquinolinium hydroxytris(pentafluorophenyl)borate, 1, and phenanthridium hydroxytris(pentafluorophenyl)borate, 2, in either CH2Cl2 or CH3CN resulted in C6F5 transfer to theisoquinolinium and phenanthridium cations, generating 2-methyl-1-(2,3,4,5,6- pentafluorophenyl)-1,2-dihydroisoquinoline, 3, and 2-methyl-1-(2,3,4,5,6-pentafluorophenyl)-1,2-dihydrophenanthridine,4, respectively. In addition, photogeneration of H2O·B(C6F5)3 resulted from 1. Photogeneration ofC6F5−C6F4H from HO−B(C6F5)3- and of C6H5−C6F4H from C6H5−B(C6F5)3- was discovered.
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