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À propos de : Phosphine-Free Hydrazone−Pd Complex as the CatalystPrecursor for a Suzuki−Miyaura Reaction under Mild AerobicConditions        

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  • Phosphine-Free Hydrazone−Pd Complex as the CatalystPrecursor for a Suzuki−Miyaura Reaction under Mild AerobicConditions
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  • Glyoxal bis(N-methyl-N-phenylhydrazone) (1) and its related compounds such as 2-pyridinecarboxaldehyde N-methyl-N-phenylhydrazone (3) were prepared and examined as ligands for theSuzuki−Miyaura cross-coupling reaction of aryl halides and arylboronic acids. We found phosphine-free catalysts, such as Pd(OAc)2/hydrazone ligand 1 or 3, to be efficient catalysts for a variety ofsubstrates to produce the coupling products in good yields.
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