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À propos de : Regioselective Synthesis of3-(2-Hydroxyaryl)pyridines via Arynes andPyridine N-Oxides        

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  • Regioselective Synthesis of3-(2-Hydroxyaryl)pyridines via Arynes andPyridine N-Oxides
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  • A variety of substituted 3-(2-hydroxyphenyl)pyridines havebeen prepared regioselectively by a transition-metal-free,mild, one-step route, which involves the reaction of pyridineN-oxides with silylaryl triflates in the presence of CsF inacetonitrile at room temperature. These reactions proceedin good yields through what appears to be a series ofrearrangements.
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