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À propos de : Diversity Synthesis Using the Complimentary Reactivity ofRhodium(II)- and Palladium(II)-Catalyzed Reactions        

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  • Diversity Synthesis Using the Complimentary Reactivity ofRhodium(II)- and Palladium(II)-Catalyzed Reactions
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  • Rhodium(II)-catalyzed reactions of aryldiazoacetates can be conducted in the presence of iodide, triflate,organoboron, and organostannane functionality, resulting in the formation of a variety of cyclopropanesor C−H insertion products with high stereoselectivity. The combination of the rhodium(II)-catalyzedreaction with a subsequent palladium(II)-catalyzed Suzuki coupling offers a novel strategy for diversitysynthesis.
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