About: Two-Photon Photochemical Generation of Reactive Enediyne

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_19/w
Subject	Article
Title	Two-Photon Photochemical Generation of Reactive Enediyne
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_19/101021jo061285m/m/web http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_19/101021jo061285m/m/print
related by	http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_19/101021jo061285m/authorship/2 http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_19/101021jo061285m/authorship/1
Author	Popik V. V. Poloukhtine Andrei
Abstract	p-Quinoid cyclopropenone-containing enediyne precursor (1) has been synthesized by monocyclopropanation of one of the triple bonds in p-dimethoxy-substituted 3,4-benzocyclodeca-1,5-diyne followedby oxidative demethylation. Cyclopropenone 1 is stable up to 90 °C but readily produces reactive enediyne2 upon single-photon (Φ300nm = 0.46) or two-photon (σ800nm = 0.5 GM) photolysis. The photoproduct 2undergoes Bergman cyclization at 40 °C with the lifetime of 88 h.
article type	research-article
is part of this journal	The Journal of Organic Chemistry

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