Abstract
| - The palladium-catalyzed formation of Z-olefins from allyliccarbonates and a variety of protected dialkyl aminomalonatesis reported. The reaction is selective for the Z-isomer, andeither acetyl, Boc, or formyl protecting groups are tolerated.The Z-olefin product can be formed regardless of whetherthe E- or Z-allylic carbonate is used as starting material.
|