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Radical-Mediated Opening of 2,3-Epoxy AlcoholsUsing Cp2TiCl: Stereoselective Construction ofQuaternary Chiral Centers
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http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/w
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Title
Radical-Mediated Opening of 2,3-Epoxy AlcoholsUsing Cp2TiCl: Stereoselective Construction ofQuaternary Chiral Centers
has manifestation of work
http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/101021jo0600961/m/print
http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/101021jo0600961/m/web
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http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/101021jo0600961/authorship/2
http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/101021jo0600961/authorship/1
http://hub.abes.fr/acs/periodical/joceah/2006/volume_71/issue_8/101021jo0600961/authorship/3
Author
Samanta Rajarshi
Das Sanjib
Chakraborty Tushar Kanti
Abstract
Radical-mediated opening of chiral 2,3-epoxy alcoholsregioselectively at the 2-position using Cp2TiCl and trappingthe intermediate radical with methyl acrylate and acrylonitrileled to the stereoselective formation of tetrasubstituted chiralcenters.
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The Journal of Organic Chemistry
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