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À propos de : Bisoxazoline-Lewis Acid-Catalyzed Direct-Electron Demandoxo-Hetero-Diels−Alder Reactions of N-Oxy-pyridine Aldehyde andKetone Derivatives        

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  • Bisoxazoline-Lewis Acid-Catalyzed Direct-Electron Demandoxo-Hetero-Diels−Alder Reactions of N-Oxy-pyridine Aldehyde andKetone Derivatives
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  • A general catalytic oxo-hetero-Diels−Alder reaction for pro-chiral aldehyde and ketone N-oxy-pyridinesis presented. The catalytic and asymmetric oxo-hetero-Diels−Alder reaction of electron-rich dienes withN-oxy-pyridine-2-carbaldehyde and ketone derivatives, catalyzed by chiral copper(II)−bisoxazolinecomplexes, gives optically active six-membered oxygen heterocycles in moderate to good yields andwith excellent enantioselectivities.
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