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À propos de : Reactions of Nitroso Hetero-Diels−AlderCycloadducts with Azides: StereoselectiveFormation of Triazolines and Aziridines        

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  • Reactions of Nitroso Hetero-Diels−AlderCycloadducts with Azides: StereoselectiveFormation of Triazolines and Aziridines
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  • The addition of azides to acylnitroso hetero-Diels−Aldercycloadducts derived from cyclopentadiene affords exo-triazolines in excellent yield. The reaction is greatly affectedby the level of alkene strain, while sterically demandingazides do not hinder the reaction. Conversion of thetriazolines to aziridines is also described.
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