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À propos de : Triazabicyclodecene: An Effective IsotopeExchange Catalyst in CDCl3        

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  • Triazabicyclodecene: An Effective IsotopeExchange Catalyst in CDCl3
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  • We describe the first effective H/D exchange reaction withacidic substrates in CDCl3 at room temperature. The particularly mild reaction conditions involved (solvent, base,and temperature) allow the chemoselective deuteration ofketones over esters. An NMR study was conducted with theaim of rationalizing the results obtained in the presence ofTBD as catalyst.
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