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À propos de : Enantioselective Total Synthesis of Phomallenic Acid C        

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  • Enantioselective Total Synthesis of Phomallenic Acid C
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  • The newly isolated bacterial FAS II inhibitor phomallenic acid C (3) was synthesized for the first timeas a 16:1 mixture of the (R)- and (S)-isomer with the diyne-allene motif constructed using a couplingunder Negishi conditions. By comparison with the synthetic sample, the natural phomallenic acid C wasestimated to be a 3.8:1 mixture of (R)-/(S)-isomers. This synthesis describes a new synthetic entry tooptically active allene diynes.
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